Ordained
Bishop | Years | Name | Current Title |
|---|
| Most Senior |
| 23 Nov 1974 |
| Archbishop Zacarias Kamwenho | Archbishop Emeritus of Lubango |
| 23 Nov 1986 |
| Archbishop José de Queirós Alves, C.SS.R. | Archbishop Emeritus of Huambo |
| 24 Jun 1990 |
| Bishop Serafim Shyngo-Ya-Hombo, O.F.M. Cap. | Bishop Emeritus of Mbanza Congo |
| 26 Aug 1996 |
| Archbishop Aldo Cavalli | Apostolic Visitor (Visitator) |
| 3 May 1998 |
| Bishop Anastácio Kahango, O.F.M. Cap. | Auxiliary Bishop Emeritus of Luanda |
| 6 Jan 2000 |
| Archbishop Gabriel Mbilingi, C.S.Sp. | Archbishop of Lubango |
| 1 Dec 2001 |
| Giovanni Angelo Cardinal Becciu | Prefect Emeritus of the Congregation for the Causes of Saints, Roman Curia |
| 3 Feb 2002 |
| Bishop Joaquim Ferreira Lopes, O.F.M. Cap. | Bishop Emeritus of Viana |
| 11 Jan 2004 |
| Archbishop Filomeno do Nascimento Vieira Dias | Archbishop of Luanda |
| 23 Oct 2005 |
| Bishop Almeida Kanda (Canda) | Bishop of Ndalatando |
| 25 Feb 2007 |
| Bishop Emílio Sumbelelo | Bishop of Viana |
| 22 Jul 2007 |
| Bishop António Francisco Jaca, S.V.D. | Bishop of Benguela |
| Most Junior |
| 24 Aug 2024 |
| Archbishop Kryspin Witold Dubiel | Apostolic Nuncio to Angola |
| 23 Jun 2024 |
| Bishop Vicente Sanombo | Bishop of Kwito-Bié |
| 24 Feb 2024 |
| Archbishop Abel Liluala | Archbishop of Pointe-Noire, Congo |
| 3 Sep 2023 |
| Bishop Martín Lasarte Topolansky, S.D.B. | Bishop of Lwena |
| 12 Aug 2023 |
| Archbishop Germano Penemote | Apostolic Nuncio to Pakistan |
| 23 Jul 2023 |
| Bishop Firmino David | Bishop of Sumbe |
| 6 Feb 2022 |
| Bishop Estêvão Binga | Bishop of Ganda |
| 30 Jan 2022 |
| Bishop Fernando Francisco | Auxiliary Bishop of Luanda |
| 23 Jan 2022 |
| Bishop António Lungieki Pedro Bengui | Auxiliary Bishop of Luanda |
| 7 Mar 2021 |
| Bishop Joaquim Nhanganga Tyombe | Bishop of Uije |
| 17 Oct 2020 |
| Archbishop Giovanni Gaspari | Apostolic Nuncio to Korea |
| 16 Aug 2020 |
| Bishop Maurício Agostinho Camuto, C.S.Sp. | Bishop of Caxito |
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